Poly[[tris(N,N-dimethylformamide)(μ4-5-nitroisophthalato)(μ3-5-nitroisophthalato)dicobalt(II)] N,N-dimethylformamide monosolvate]
نویسندگان
چکیده
In the polymeric title compound, [Co(2)(C(3)H(7)NO)(3)(C(8)H(3)NO(6))(2)]·C(3)H(7)NO, one 5-nitro-isophthalate dianion has its two carboxyl-ate groups chelating to one Co(II) atom while simultaneously coordinating to another metal atom in a μ(4)-bridging mode. The other 5-nitro-isophthalte dianion has one carboxyl-ate group chelating to a metal atom whereas the other bridges two metal atoms in a μ(3)-bridging mode. Both metal atoms show an octa-hedral coordination. The polymer adopts a layer motif, with the lattice dimethyl-formamide mol-ecules occupying the space between adjacent layers.
منابع مشابه
Poly[(μ6-benzene-1,3,5-tricarboxylato-κ6 O 1:O 1′:O 3:O 3′:O 5:O 5′)tris(N,N-dimethylformamide-κO)tris(μ3-formato-κ2 O:O′)trimagnesium(II)]
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